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C-H bond : ウィキペディア英語版
Carbon–hydrogen bond
The carbon-hydrogen bond (C–H bond) is a bond between carbon and hydrogen atoms that can be found in many organic compounds. This bond is a covalent bond meaning that carbon shares its outer valence electrons with up to four hydrogens. This completes both of their outer shells making them stable. Carbon–hydrogen bonds have a bond length of about 1.09 Å (1.09 × 10−10 m) and a bond energy of about 413 kJ/mol (see table below). Using Pauling's scale—C (2.55) and H (2.2)—the electronegativity difference between these two atoms is 0.35. Because of this small difference in electronegativities, the C−H bond is generally regarded as being non-polar. In structural formulas of molecules, the hydrogen atoms are often omitted. Compound classes consisting solely of C-H bonds and C–C bonds are alkanes, alkenes, alkynes, and aromatic hydrocarbons. Collectively they are known as hydrocarbons.
==Reactions==
(詳細はcarbon acids, the C−H bond can be sufficiently acidic for proton removal. Unactivated C−H bonds are found in alkanes and are not adjacent to a heteroatom (O, N, Si, etc.). Such bonds usually only participate in radical substitution. Many enzymes are known, however, to affect these reactions.〔Bollinger, J. M. Jr., Broderick, J. B. "Frontiers in enzymatic C-H-bond activation" Current Opinion in Chemical Biology 2009, vol. 13, page 51-7. 〕
Although the C−H bond is one of the strongest, it varies over 30% in magnitude for fairly stable organic compounds, even in the absence of heteroatoms.〔http://www.cem.msu.edu/~reusch/OrgPage/bndenrgy.htm#dissbe〕〔Yu-Ran Luo and Jin-Pei Cheng "Bond Dissociation Energies" in CRC Handbook of Chemistry and Physics, 96th Edition


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Carbon–hydrogen bond」の詳細全文を読む



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